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Oxidative Coupling of Benzylamines to Imines by Molecular Oxygen Catalyzed by Cobalt(II) beta-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin
Alternative Title空气中β-四三氟甲基-meso-四苯基钴卟啉催化苄胺氧化偶联为亚胺
Zhao S(赵帅); Liu C(刘超); Guo Y(郭勇); Xiao JC(肖吉昌); Chen QY(陈庆云)
2014
Source PublicationJ. Org. Chem.
Volume79Issue:18Pages:8926-8931
AbstractOxidative coupling of benzylamines to imines by molecular oxygen is efficiently realized in the presence of very low catalyst loadings of Co(II) beta-tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin. Due to the effect of four beta-CF3 groups, the catalyst shows good selectivity and very high turnover number. The reaction is easily scaled up and may provide a convenient way to prepare many imines in large scale.
Subject Area氟化学
DOI10.1021/jo5017212
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Indexed BySCI
Language英语
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Cited Times:32[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.sioc.ac.cn/handle/331003/38808
Collection中科院有机氟化学重点实验室
Corresponding AuthorChen QY(陈庆云)
Affiliation中科院上海有机化学研究所
Recommended Citation
GB/T 7714
Zhao S,Liu C,Guo Y,et al. Oxidative Coupling of Benzylamines to Imines by Molecular Oxygen Catalyzed by Cobalt(II) beta-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin[J]. J. Org. Chem.,2014,79(18):8926-8931.
APA 赵帅,刘超,郭勇,肖吉昌,&陈庆云.(2014).Oxidative Coupling of Benzylamines to Imines by Molecular Oxygen Catalyzed by Cobalt(II) beta-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin.J. Org. Chem.,79(18),8926-8931.
MLA 赵帅,et al."Oxidative Coupling of Benzylamines to Imines by Molecular Oxygen Catalyzed by Cobalt(II) beta-Tetrakis(trifluoromethyl)-meso-tetraphenylporphyrin".J. Org. Chem. 79.18(2014):8926-8931.
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