SIOC OpenIR  > 中科院有机氟化学重点实验室
beta-Perfluoroalkylated meso-Aryl-Substituted Subporphyrins: Synthesis and Properties
其他题名β-全氟烷基-meso-芳基取代亚卟啉: 合成和性质
Zhao S(赵帅); Liu C(刘超); Guo Y(郭勇); Xiao JC(肖吉昌); Chen QY(陈庆云)
2014
发表期刊Synthesis
卷号46期号:12页码:1674-1688
摘要A convenient and effective synthesis of various novel beta-perfluoroalkylated subporphyrins has been developed. beta-Trifluoromethylated subporphyrins were efficiently synthesized by the reaction of brominated subporphyrins with FSO2CF2CO2Me/CuI [with or without Pd(dba)(2)]. Potentially valuable beta-perfluoroalkylated, beta-monotetrafluorobenzo, and beta-monotrifluorobenzo subporphyrins were successfully obtained by a modified sulfinatodehalogenation reaction. Photophysical and electrochemical studies on several typical perfluoroalkylated subporphyrins demonstrated that beta-hexakis-trifluoromethylated subporphyrins show an obviously red-shifted UV/Vis absorption band that arises from macrocycle nonplanar distortion induced by trifluoromethyl groups, but this distortion is not so severe as that of the corresponding beta-octakis(trifluoromethyl)meso-tetraphenylporphyrin. This was supported by their redox potential data. In addition, beta-monotrifluorobenzo subporphyrin exhibits a special fluorescence spectrum of vibronic structure.
学科领域氟化学
DOI10.1055/s-0033-1341055
URL查看原文
收录类别SCI
语种英语
引用统计
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/38807
专题中科院有机氟化学重点实验室
通讯作者Chen QY(陈庆云)
作者单位中科院上海有机化学研究所
推荐引用方式
GB/T 7714
Zhao S,Liu C,Guo Y,et al. beta-Perfluoroalkylated meso-Aryl-Substituted Subporphyrins: Synthesis and Properties[J]. Synthesis,2014,46(12):1674-1688.
APA 赵帅,刘超,郭勇,肖吉昌,&陈庆云.(2014).beta-Perfluoroalkylated meso-Aryl-Substituted Subporphyrins: Synthesis and Properties.Synthesis,46(12),1674-1688.
MLA 赵帅,et al."beta-Perfluoroalkylated meso-Aryl-Substituted Subporphyrins: Synthesis and Properties".Synthesis 46.12(2014):1674-1688.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2014236.pdf(528KB)期刊论文作者接受稿开放获取CC BY-NC-SA请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[赵帅]的文章
[刘超]的文章
[郭勇]的文章
百度学术
百度学术中相似的文章
[赵帅]的文章
[刘超]的文章
[郭勇]的文章
必应学术
必应学术中相似的文章
[赵帅]的文章
[刘超]的文章
[郭勇]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。