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学科主题: 物理有机化学
题名: A 1,4-Diphenyl-1,2,3-Triazole-Based beta-Turn Mimic Constructed by Click Chemistry
其他题名: 点击化学构筑一种基于1,3-二苯基1,2,3-三氮唑的β-转角模拟结构
作者: Wu CF(吴春芳) ; Zhao X(赵新) ; Lan WX(蓝文贤) ; Cao CY(曹春阳) ; Liu JT(刘金涛) ; Jiang XK(蒋锡夔) ; Li ZT(黎占亭)
通讯作者: 赵新 ; 黎占亭
刊名: J. Org. Chem.
发表日期: 2012
卷: 77, 期:9, 页:4261-4270
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A series of 1,4-diphenyl-1,2,3-triazole-incorporated amide derivatives have been designed and prepared. Xray crystallographic and (1D and 2D) 1H NMR studies reveal that these compounds fold into stable U-shaped conformations driven by three-center intramolecular C-H center dot center dot center dot O hydrogen-bonding formed between the triazole C-5 H atom and the two ether O atoms. Such folded structures make this 1,4-diphenyl-1,2,3-triazole skeleton a good candidate to be used as beta-turn mimic. To prove this, the formation of a beta-hairpin structure induced by this beta-turn motif has been further demonstrated.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000303492300009
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28699
Appears in Collections:物理有机化学研究室_期刊论文

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Recommended Citation:
Wu CF,Zhao X,Lan WX,et al. A 1,4-Diphenyl-1,2,3-Triazole-Based beta-Turn Mimic Constructed by Click Chemistry[J]. J. Org. Chem.,2012,77(9):4261-4270.
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