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学科主题: 天然产物有机化学
题名: Development of a Nonenzymatic Kinetic Resolution of alpha-Allenic Alcohols
其他题名: 发展非酶催化的alpha-联烯醇的环化异构化动力学拆分
作者: Wang Y(王燕) ; Rob Hoen ; Hong R(洪然)
通讯作者: 洪然
刊名: Synlett
发表日期: 2012
期: 19, 页:2729-2734
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 西班牙GP Pharm
英文摘要: This personal viewpoint lays out the development of a silver-catalyzed kinetic resolution of alpha-allenic alcohols inspired by the biomimetic synthesis of natural products. The corresponding selectivity factor (s) indicates that this resolution protocol can deliver chiral allenic alcohols and 2,5-dihydrofurans in high enantioselectivity with synthetically applicable isolated yields. The broad substrate scope makes it an attractive approach for building synthetically useful chiral building blocks. From the recent progress in allene chemistry, silver was considered as an anion metathesis reagent to prepare highly efficient Au catalysts. Our discovery of the unique reactivity of a chiral silver phosphate should stimulate more interesting discoveries in this field.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000311492100002
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28645
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Wang Y,Rob Hoen,Hong R. Development of a Nonenzymatic Kinetic Resolution of alpha-Allenic Alcohols[J]. Synlett,2012(19):2729-2734.
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