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学科主题: 天然产物有机化学
题名: Mechanistic Investigations of a Palladium-Diene Catalyzed Suzuki-Miyaura Cross-Coupling Reaction
其他题名: 钯双烯催化的Suzuki-Miyaura偶联反应的机理研究
作者: He XS(贺小双) ; Zhang SS(张曙盛) ; Guo YL(郭寅龙) ; Wang HY(王昊阳) ; Lin GQ(林国强)
通讯作者: 郭寅龙 ; 林国强
刊名: Organometallics
发表日期: 2012
卷: 31, 期:8, 页:2945-2948
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: The mechanism of the first example of a palladium diene catalyzed asymmetric Suzuki-Miyaura cross-coupling reaction has been validated, with the key palladium intermediates captured and characterized. The identified species corresponding to each catalytic step were firmly associated with the diene ligand in our observations. In the ESI-MS/MS experiments by CID (collision-induced dissociation), the fragmentation of the gas-phase transmetalation species was consistent with the product-yielding process in the reductive elimination step and thus revealed the catalytically active species of the reaction system.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000303071100002
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28601
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
He XS,Zhang SS,Guo YL,et al. Mechanistic Investigations of a Palladium-Diene Catalyzed Suzuki-Miyaura Cross-Coupling Reaction[J]. Organometallics,2012,31(8):2945-2948.
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