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学科主题: 天然产物有机化学
题名: Easily accessible chiral dicyclopentadiene ligands for rhodium-catalyzed enantioselective 1,4-addition reactions
其他题名: 简单易得的手性二聚环戊二烯类配体在铑催化的不对称1,4-加成反应中的应用
作者: Shao C(邵成) ; Yu HJ(于宏杰) ; Feng CG(冯陈国) ; Wang R(王锐) ; Lin GQ(林国强)
通讯作者: 王锐 ; 林国强
刊名: Tetrahedron Lett.
发表日期: 2012
卷: 53, 期:22, 页:2733-2735
收录类别: SCI
部门归属: 兰州大学; 中科院上海有机化学研究所
英文摘要: A variety of novel C-1-symmetric chiral diene ligands based on the dicyclopentadiene (DCP) skeleton were easily prepared from commercially available DCP. The application of these diene ligands in the rhodium-catalyzed asymmetric 1,4-addition of arylboronic acids to alpha,beta-unsaturated carbonyl compounds has been examined and excellent enantioselectivities (up to 97% ee) as well as good yields were achieved under mild reaction conditions. (C) 2012 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000303953200016
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28599
Appears in Collections:中科院天然产物有机化学重点实验室_期刊论文

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Recommended Citation:
Shao C,Yu HJ,Feng CG,et al. Easily accessible chiral dicyclopentadiene ligands for rhodium-catalyzed enantioselective 1,4-addition reactions[J]. Tetrahedron Lett.,2012,53(22):2733-2735.
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