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学科主题: 生命有机化学 ; 天然产物有机化学
题名: Total Syntheses of Anominine and Tubingensin A
其他题名: Anominine and Tubingensin A的全合成
作者: Bian M(卞明) ; Wang Z(王震) ; Xiong XC(熊小春) ; Sun Y(孙域) ; MATERA CARLO ; NICOLAOU K C ; Li A(李昂)
通讯作者: NICOLAOU K C ; 李昂
刊名: J. Am. Chem. Soc.
发表日期: 2012
卷: 134, 期:19, 页:8078-8081
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 美国Scripps研究所; 美国加州大学圣地亚哥分校
英文摘要: A divergent strategy for the total syntheses of the indole terpenoid anominine (1) and its natural congener tubingensin A (2) has been developed. The common intermediate 11 bearing all of the required stereogenic centers for both natural products was first assembled by employing a Ueno-Stork radical cyclization and a Sc(OTf)(3)-mediated Mukaiyama aldol reaction to form the key C-C bonds in a stereocontrolled manner. The route to anominine features a radical deoxygenation followed by an efficient side-chain installation, while the path to tubingensin A exploits a CuOTf-promoted 6 pi-electrocyclization/aromatization sequence to forge the central region of the pentacyclic scaffold.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000304027100020
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28527
Appears in Collections:生命有机化学国家重点实验室_期刊论文

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Recommended Citation:
Bian M,Wang Z,Xiong XC,et al. Total Syntheses of Anominine and Tubingensin A[J]. J. Am. Chem. Soc.,2012,134(19):8078-8081.
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