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A new procedure for the synthesis of pi-conjugated polymers via ligand-free iron(III)-catalyzed oxidative homocoupling reaction of grignard reagents
其他题名无配体下三价铁催化氧化格式试剂自偶联反应制备共轭聚合物
Yuan C(袁超); Fang Q(房强)
2012
发表期刊RSC Adv.
ISSN2046-2069
卷号2期号:21页码:8055-8060
摘要The FeCl3-catalyzed oxidative homocoupling reaction of Grignard reagents was used for the synthesis of p-conjugated polymers in this study. In the presence of an oxidant (1,2-dichloroethane), three polymers were successfully prepared, namely, poly(9,9-dioctylfluorene-2,7-diyl), poly(N-butylcarbazol-3,6-diyl) and poly(2,5-dihexyloxyphenylene-1,4-diyl). In comparison with the polymers obtained by Suzuki coupling, the polymers in this work showed no obvious difference in chemical structures or optical properties. On the basis of the relatively low cost of iron(III)-catalysts and Grignard reagents, this route would be an attractive alternative for the synthesis of pi-conjugated polymers.
学科领域高分子化学
部门归属中科院上海有机化学研究所
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收录类别SCI
语种英语
WOS记录号WOS:000307792200021
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被引频次:5[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/28439
专题高分子材料研究室
通讯作者Fang Q(房强)
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Yuan C,Fang Q. A new procedure for the synthesis of pi-conjugated polymers via ligand-free iron(III)-catalyzed oxidative homocoupling reaction of grignard reagents[J]. RSC Adv.,2012,2(21):8055-8060.
APA 袁超,&房强.(2012).A new procedure for the synthesis of pi-conjugated polymers via ligand-free iron(III)-catalyzed oxidative homocoupling reaction of grignard reagents.RSC Adv.,2(21),8055-8060.
MLA 袁超,et al."A new procedure for the synthesis of pi-conjugated polymers via ligand-free iron(III)-catalyzed oxidative homocoupling reaction of grignard reagents".RSC Adv. 2.21(2012):8055-8060.
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