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New ladder-type conjugated polymer with broad absorption, high thermal stability, and low band gap
其他题名New ladder-type conjugated polymer with broad absorption, high thermal stability, and low band gap
Wang ST(王世涛); Hong W(洪巍); Ren SD(任申冬); Li J(李杰); Wang M(王毛); Gao XK(高希珂); Li HX(李洪祥)
2012
发表期刊J. Polym. Sci. Pol. Chem.
ISSN0887-624X
卷号50期号:20页码:4272-4276
摘要New ladder-type p-conjugated polymer poly{6-alkyl-pyrrolo[3,2-b:4,5-b']bis-[1,4]benzothiazine} (PPBBTZ) was synthesized through a simple method. PPBBTZ showed good solubility in organic solvents (such as chloroform, tetrahydrofuran, chlorobenzene, o-dichlorobenzene) and high thermal stability (decomposition temperatures up to 323 degrees C and 299 degrees C in nitrogen and air, respectively). The highest occupied molecular orbital and lowest unoccupied molecular orbital energy level estimated from electrochemistry result and absorption spectrum were -5.46 and -3.81 eV, respectively, with a band gap of 1.65 eV. More interestingly, PPBBTZ displayed broad absorption from ultraviolet to visible light regions (200750 nm). These properties suggested PPBBTZ was a good candidate in opto-electronics. (c) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
学科领域高分子化学
部门归属中科院上海有机化学研究所; 华东理工大学
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收录类别SCI
语种英语
WOS记录号WOS:000308427600015
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被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/28435
专题高分子材料研究室
通讯作者Li HX(李洪祥)
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GB/T 7714
Wang ST,Hong W,Ren SD,et al. New ladder-type conjugated polymer with broad absorption, high thermal stability, and low band gap[J]. J. Polym. Sci. Pol. Chem.,2012,50(20):4272-4276.
APA 王世涛.,洪巍.,任申冬.,李杰.,王毛.,...&李洪祥.(2012).New ladder-type conjugated polymer with broad absorption, high thermal stability, and low band gap.J. Polym. Sci. Pol. Chem.,50(20),4272-4276.
MLA 王世涛,et al."New ladder-type conjugated polymer with broad absorption, high thermal stability, and low band gap".J. Polym. Sci. Pol. Chem. 50.20(2012):4272-4276.
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