SIOC OpenIR  > 高分子材料研究室
Tridentate ligands and beyond in group IV metal alpha-olefin homo-/co-polymerization catalysis
其他题名三齿及多齿配体的第IV族金属配合物在α-烯烃均聚/共聚的催化作用
REDSHAW CARL; Tang Y(唐勇)
2012
发表期刊Chem. Soc. Rev.
ISSN0306-0012
卷号41期号:12页码:4484-4510
摘要The opening up of new markets, particularly in the Far East, is expected to increase the industrial demand for more (and new) plastic materials. In turn, this will drive the need for further catalyst development, with increased efficiency and with the capacity to easily control the resulting polymer properties being high on the agenda. With this in mind, tailoring the pre-catalyst structure has proved to be a very successful strategy, and has allowed for the elucidation of a number of structure-activity trends. A particularly fruitful synthetic avenue has been the deployment of multi-dentate ancillary ligands bearing one or more substituents containing additional functionality, capable of weakly binding to the metal. Such a method is versatile and allows for the incorporation of a wide range of functionality. Furthermore, benefits of such an approach include the ability to control the % incorporation of co-monomers, in situ screening, low co-catalyst loadings (versus activity enhancement) as well as control over the resultant polymer structure. This review underlines the efforts made in the last few years with regard to the use of tridentate ligands and beyond in the field of a-olefin polymerization using catalytic systems based on group IV metals.
学科领域高分子化学
部门归属中科院上海有机化学研究所; University of East Anglia
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000304555700007
引用统计
被引频次:109[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/28421
专题高分子材料研究室
通讯作者REDSHAW CARL; Tang Y(唐勇)
推荐引用方式
GB/T 7714
REDSHAW CARL,Tang Y. Tridentate ligands and beyond in group IV metal alpha-olefin homo-/co-polymerization catalysis[J]. Chem. Soc. Rev.,2012,41(12):4484-4510.
APA REDSHAW CARL,&唐勇.(2012).Tridentate ligands and beyond in group IV metal alpha-olefin homo-/co-polymerization catalysis.Chem. Soc. Rev.,41(12),4484-4510.
MLA REDSHAW CARL,et al."Tridentate ligands and beyond in group IV metal alpha-olefin homo-/co-polymerization catalysis".Chem. Soc. Rev. 41.12(2012):4484-4510.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2012260.pdf(3147KB) 开放获取--请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[REDSHAW CARL]的文章
[唐勇]的文章
百度学术
百度学术中相似的文章
[REDSHAW CARL]的文章
[唐勇]的文章
必应学术
必应学术中相似的文章
[REDSHAW CARL]的文章
[唐勇]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。