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学科主题: 高分子化学
题名: Tridentate ligands and beyond in group IV metal alpha-olefin homo-/co-polymerization catalysis
其他题名: 三齿及多齿配体的第IV族金属配合物在α-烯烃均聚/共聚的催化作用
作者: REDSHAW CARL ; Tang Y(唐勇)
通讯作者: REDSHAW CARL ; 唐勇
刊名: Chem. Soc. Rev.
发表日期: 2012
卷: 41, 期:12, 页:4484-4510
收录类别: SCI
部门归属: 中科院上海有机化学研究所; University of East Anglia
英文摘要: The opening up of new markets, particularly in the Far East, is expected to increase the industrial demand for more (and new) plastic materials. In turn, this will drive the need for further catalyst development, with increased efficiency and with the capacity to easily control the resulting polymer properties being high on the agenda. With this in mind, tailoring the pre-catalyst structure has proved to be a very successful strategy, and has allowed for the elucidation of a number of structure-activity trends. A particularly fruitful synthetic avenue has been the deployment of multi-dentate ancillary ligands bearing one or more substituents containing additional functionality, capable of weakly binding to the metal. Such a method is versatile and allows for the incorporation of a wide range of functionality. Furthermore, benefits of such an approach include the ability to control the % incorporation of co-monomers, in situ screening, low co-catalyst loadings (versus activity enhancement) as well as control over the resultant polymer structure. This review underlines the efforts made in the last few years with regard to the use of tridentate ligands and beyond in the field of a-olefin polymerization using catalytic systems based on group IV metals.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000304555700007
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28421
Appears in Collections:高分子材料研究室_期刊论文

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Recommended Citation:
REDSHAW CARL,Tang Y. Tridentate ligands and beyond in group IV metal alpha-olefin homo-/co-polymerization catalysis[J]. Chem. Soc. Rev.,2012,41(12):4484-4510.
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