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学科主题: 高分子化学
题名: Influence of Intermolecular N-H center dot center dot center dot pi Interactions on Molecular Packing and Field-Effect Performance of Organic Semiconductors
其他题名: Influence of Intermolecular N-H center dot center dot center dot pi Interactions on Molecular Packing and Field-Effect Performance of Organic Semiconductors
作者: Zhao HP(赵华平) ; Jiang L(江浪) ; Dong HL(董焕丽) ; Li HX(李洪祥) ; Hu WP(胡文平) ; ONG BENG S
通讯作者: 李洪祥 ; 胡文平 ; ONG BENG S
刊名: ChemPhysChem
发表日期: 2009
卷: 10, 期:13, 页:2345-2348
收录类别: SCI
部门归属: 上海有机所; 化学所
英文摘要: Charge transport in organic semiconductors is strongly dependent on their molecular packing modes in the solid state. Therefore, understanding the relationship between molecular packing and charge transport is imperative both experimentally and theoretically. However, so far, the fundamental effects of solid-state packing and molecular interactions (e.g. N-H center dot center dot center dot pi) on charge transport need further elucidation. Herein, indolo[3,2-b]carbazole (ICZ) and a derivative thereof are used as examples to approach this scientific target. An interesting insight obtained thereby is that N-H center dot center dot center dot pi interactions among ICZ molecules facilitate charge transport for higher mobility. Subtle changes in the of N-H center dot center dot center dot pi interactions can significantly influence both the molecular packing and the charge-transport properties. Therefore, a method for exploiting intermolecular N-H center dot center dot center dot pi interactions would yield novel molecular systems with designable characteristics.
语种: 英语
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WOS记录号: WOS:000269979600026
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28367
Appears in Collections:高分子材料研究室_期刊论文

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Recommended Citation:
Zhao HP,Jiang L,Dong HL,et al. Influence of Intermolecular N-H center dot center dot center dot pi Interactions on Molecular Packing and Field-Effect Performance of Organic Semiconductors[J]. ChemPhysChem,2009,10(13):2345-2348.
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