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学科主题: 氟化学
题名: Preparation of Trifluorostyrenes via Palladium-Catalyzed Coupling of Arylboronic Acids with Chloro- and Bromotrifluoroethylene
其他题名: 通过三氟氯乙烯和三氟溴乙烯与硼酸的钯催化偶联反应制备三氟苯乙烯
作者: XU CHUNFA ; CHEN SHENG ; Lv L(吕龙) ; Shen QL(沈其龙)
通讯作者: 吕龙 ; 沈其龙
刊名: J. Org. Chem.
发表日期: 2012
卷: 77, 期:22, 页:10314-10320
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A highly efficient and cost-effective method for the preparation of alpha,beta,beta-trifluorostyrene (TFS) and its derivatives is described. The method required only 0.2 mol % of Pd(dba)(2) and 0.4 mol % of (PBu3)-Bu-t and occurred to full conversion within 2.0 h. With this method, a wide range of arylboronic acids were efficiently incorporated to generate alpha,beta,beta-trifluorostyrene derivatives.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000311073000037
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28351
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
XU CHUNFA,CHEN SHENG,Lv L,et al. Preparation of Trifluorostyrenes via Palladium-Catalyzed Coupling of Arylboronic Acids with Chloro- and Bromotrifluoroethylene[J]. J. Org. Chem.,2012,77(22):10314-10320.
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