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学科主题: 氟化学 ; 金属有机化学
题名: Palladium-catalyzed allylation of 2,2,2-thfluoroethyl phenyl sulfone, a potential 2,2,2-trifluoroethyl pronucleophile
其他题名: 钯催化下对潜在的亲核2,2,2-三氟乙基化试剂前体2,2,2-三氟乙基苯砜的烯丙基化反应
作者: Zhang W(张伟) ; Zhao YC(赵延川) ; Ni CF(倪传法) ; Thomas Mathew ; Hu JB(胡金波)
通讯作者: Thomas Mathew ; 胡金波
刊名: Tetrahedron Lett.
发表日期: 2012
卷: 53, 期:48, 页:6565-6568
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 美国南加州大学
英文摘要: A palladium-catalyzed allylation reaction of PhSO2CH2CF3 (2) with a variety of allyl carbonates has been successfully developed for selective 2,2,2-trifluoroethylation under neutral conditions. With this method, the 1-phenylsulfonyl-2,2,2-trifluoroethyl moiety was efficiently transferred into organic compounds without the competing 13-elimination of fluoride, to afford a range of mono-allylated and di-allylated compounds. (C) 2012 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000311021600023
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28349
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Zhang W,Zhao YC,Ni CF,et al. Palladium-catalyzed allylation of 2,2,2-thfluoroethyl phenyl sulfone, a potential 2,2,2-trifluoroethyl pronucleophile[J]. Tetrahedron Lett.,2012,53(48):6565-6568.
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