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学科主题: 氟化学
题名: Bis(perfluoroalkyl) Phosphino-Oxazoline: A Modular, Stable, Strongly pi-Accepting Ligand for Asymmetric Catalysis
其他题名: 全氟烷基取代的噁唑类配体: 一种新的可修饰的、稳定的、强吸电子的配体及其在不对称反应中的应用
作者: Hu ZJ(胡宗剑) ; Li YG(李玉光) ; Liu K(刘凯) ; Shen QL(沈其龙)
通讯作者: 沈其龙
刊名: J. Org. Chem.
发表日期: 2012-01-01
卷: 77, 期:18, 页:7957-7967
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A new class of stable, strongly pi-accepting and modular bis(perfluoroalkyl)-phosphine-oxazoline ligands (FOX) as CO mimics was prepared. It was demonstrated that these ligands, when coordinated to palladium catalysts, promote the asymmetric alkylation of monosubstituted allyl substrates with excellent regio- and enantioselectivity. Solid and solution structure analysis of the FOX-ligated Pd-allyl intermediate reveals that the combination of relative steric and strong trans influences presented by the P(CF3)(2) moiety gave rise to the excellent selectivity.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000308957700018
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28339
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Hu ZJ,Li YG,Liu K,et al. Bis(perfluoroalkyl) Phosphino-Oxazoline: A Modular, Stable, Strongly pi-Accepting Ligand for Asymmetric Catalysis[J]. J. Org. Chem.,2012,77(18):7957-7967.
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