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学科主题: 氟化学
题名: Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur
其他题名: 末端炔烃的无金属氧化的三氟甲基巯基化反应
作者: Chen C(陈超) ; Chu LL(储玲玲) ; Qing FL(卿凤翎)
通讯作者: 卿凤翎
刊名: J. Am. Chem. Soc.
发表日期: 2012
卷: 134, 期:30, 页:12454-12457
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 东华大学
英文摘要: A metal-free oxidative trifluoromethyl-thiolation of terminal alkynes using readily available CF3SiMe3 and elemental sulfur at room temperature has been developed. This reaction provides an efficient and convenient method for the preparation of alkynyl trifluoromethyl sulfides bearing a wide range of functional groups. Preliminary investigation revealed that elemental sulfur instead of air acted as the oxidant.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000306942600033
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28325
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Chen C,Chu LL,Qing FL. Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur[J]. J. Am. Chem. Soc.,2012,134(30):12454-12457.
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