| Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur | |
| Alternative Title | 末端炔烃的无金属氧化的三氟甲基巯基化反应 |
| Chen C(陈超); Chu LL(储玲玲); Qing FL(卿凤翎) | |
| 2012 | |
| Source Publication | J. Am. Chem. Soc.
 |
| ISSN | 0002-7863 |
| Volume | 134Issue:30Pages:12454-12457 |
| Abstract | A metal-free oxidative trifluoromethyl-thiolation of terminal alkynes using readily available CF3SiMe3 and elemental sulfur at room temperature has been developed. This reaction provides an efficient and convenient method for the preparation of alkynyl trifluoromethyl sulfides bearing a wide range of functional groups. Preliminary investigation revealed that elemental sulfur instead of air acted as the oxidant. |
| Subject Area | 氟化学 |
| Department | 中科院上海有机化学研究所; 东华大学 |
| URL | 查看原文 |
| Indexed By | SCI |
| Language | 英语 |
| WOS ID | WOS:000306942600033 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.sioc.ac.cn/handle/331003/28325 |
| Collection | 中科院有机氟化学重点实验室 |
| Corresponding Author | Qing FL(卿凤翎) |
| Recommended Citation GB/T 7714 | Chen C,Chu LL,Qing FL. Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur[J]. J. Am. Chem. Soc.,2012,134(30):12454-12457. |
| APA | 陈超,储玲玲,&卿凤翎.(2012).Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur.J. Am. Chem. Soc.,134(30),12454-12457. |
| MLA | 陈超,et al."Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur".J. Am. Chem. Soc. 134.30(2012):12454-12457. |
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| File Name/Size | DocType | Version | Access | License | ||
| 2012416.pdf（334KB） | 开放获取 | -- | Application Full Text | |||
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