Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur

	Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur
其他题名	末端炔烃的无金属氧化的三氟甲基巯基化反应
	Chen C(陈超); Chu LL(储玲玲); Qing FL(卿凤翎)
	2012
发表期刊	J. Am. Chem. Soc.
ISSN	0002-7863
卷号	134 期号:30 页码:12454-12457
摘要	A metal-free oxidative trifluoromethyl-thiolation of terminal alkynes using readily available CF3SiMe3 and elemental sulfur at room temperature has been developed. This reaction provides an efficient and convenient method for the preparation of alkynyl trifluoromethyl sulfides bearing a wide range of functional groups. Preliminary investigation revealed that elemental sulfur instead of air acted as the oxidant.
学科领域	氟化学
部门归属	中科院上海有机化学研究所; 东华大学
URL	查看原文
收录类别	SCI
语种	英语
WOS记录号	WOS:000306942600033
引用统计
文献类型	期刊论文
条目标识符	http://ir.sioc.ac.cn/handle/331003/28325
专题	中科院有机氟化学重点实验室
通讯作者	Qing FL(卿凤翎)
推荐引用方式 GB/T 7714	Chen C,Chu LL,Qing FL. Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur[J]. J. Am. Chem. Soc.,2012,134(30):12454-12457.
APA	陈超,储玲玲,&卿凤翎.(2012).Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur.J. Am. Chem. Soc.,134(30),12454-12457.
MLA	陈超,et al."Metal-Free Oxidative Trifluoromethylthiolation of Terminal Alkynes with CF3SiMe3 and Elemental Sulfur".J. Am. Chem. Soc. 134.30(2012):12454-12457.

条目包含的文件
文件名称/大小	文献类型	版本类型	开放类型	使用许可
2012416.pdf（334KB）			开放获取	--	请求全文