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学科主题: 氟化学
题名: Regiospecific and diastereoselective aldol reaction of chiral N-sulfinyl metalloenamines with alpha,beta-unsaturated trifluoromethyl ketones: Asymmetric synthesis of tertiary trifluoromethyl allylic carbinols
其他题名: 手性N-亚磺酰酮亚胺与α,β-不饱和三氟甲基酮的区域和立体选择性aldol反应
作者: Liu ZJ(刘振江) ; Zhang F(张帆) ; Liu JT(刘金涛)
通讯作者: 刘金涛
刊名: J. Fluor. Chem.
发表日期: 2012
卷: 133, 页:102-107
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 上海理工学院
英文摘要: Regiospecific and diastereoselective aldol type reaction of chiral N-sulfinyl metalloenamines with alpha,beta-unsaturated trifluoromethyl ketones was reported, which affords the corresponding tertiary trifluoromethyl allylic carbinols in high yields with good diastereoselectivities (dr up to 90:10). The reduction of the condensation product 3a with LiBHEt3 and Catecholborane provides CF3-substituted syn- and anti-1,3-amino alcohols 5a and 5b in high yields with excellent diastereoselectivities (dr > 99:1). (C) 2011 Elsevier B.V. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000300469500015
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28303
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Liu ZJ,Zhang F,Liu JT. Regiospecific and diastereoselective aldol reaction of chiral N-sulfinyl metalloenamines with alpha,beta-unsaturated trifluoromethyl ketones: Asymmetric synthesis of tertiary trifluoromethyl allylic carbinols[J]. J. Fluor. Chem.,2012,133:102-107.
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