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学科主题: 氟化学
题名: Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkynes and Aryl Boronic Acids Using (Trifluoromethyl)trimethylsilane
其他题名: 铜催化末端炔基和芳基硼酸的氧化三氟甲基化反应
作者: Jiang XL(蒋学良) ; Chu LL(储玲玲) ; Qing FL(卿凤翎)
通讯作者: 卿凤翎
刊名: J. Org. Chem.
发表日期: 2012
卷: 77, 期:3, 页:1251-1257
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 东华大学
英文摘要: Trifluoromethylated acetylenes and arenes are widely applicable in the synthesis of pharmaceuticals and agrochemicals. In 2010, our group has reported the copper-mediated oxidative trifluomethylation of terminal alkynes and aryl boronic acids. This method allows a wide range of functional group tolerant trifluoromethylated acetylenes and arenes to be easily prepared. After the preliminary mechanistic studies of the oxidative trifluoromethylation of terminal alkyne, an efficient copper-catalyzed oxidative trifluoromethylation of terminal alkynes and aryl boronic acids has been developed. The catalytic protocol is successfully achieved by adding both the substrate and a portion of CF3TMS slowly using a syringe pump to the reaction mixture.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000300462700004
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28285
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Jiang XL,Chu LL,Qing FL. Copper-Catalyzed Oxidative Trifluoromethylation of Terminal Alkynes and Aryl Boronic Acids Using (Trifluoromethyl)trimethylsilane[J]. J. Org. Chem.,2012,77(3):1251-1257.
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