中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 中科院有机氟化学重点实验室  > 期刊论文
学科主题: 氟化学
题名: Au(I)-Catalyzed Intramolecular Hydroamination of the Fluorinated N '-Aryl-N-Propargyl Amidines: Mild Conditions for the Synthesis of 2-Fluoroalkyl Imidazole Derivatives
其他题名: 一价金催化的含氟N-芳基-N'-炔基脒类化合物的分子内胺氢化反应: 一种合成2-氟烷基取代的咪唑衍生物的简便方法
作者: Li S(李珊) ; Li ZK(李正珂) ; Yuan YF(袁亚芬) ; Peng DJ(彭东杰) ; Li YJ(李亚军) ; Zhang LS(张里斯) ; Wu YM(吴永明)
通讯作者: 吴永明
刊名: Org. Lett.
发表日期: 2012-01-01
卷: 14, 期:4, 页:1130-1133
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 华中科技大学
英文摘要: The gold(I)-catalyzed synthesis of 2-fluoroalkyl imidazole derivatives was developed. Catalyzed by gold(I), propargyl amidines underwent a 5-exo-dig cyclization to afford 2-fluoroalkyl-5-methyl imidazoles. Also, 2-fluoroalkyl imidazole-5-carbaldehydes were obtained in the presence of NIS. A mechanism investigation manifested the probable process and the carbonyl oxygen derived from O-2.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000300339800045
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28281
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2012186.pdf(264KB)----开放获取--View Download

Recommended Citation:
Li S,Li ZK,Yuan YF,et al. Au(I)-Catalyzed Intramolecular Hydroamination of the Fluorinated N '-Aryl-N-Propargyl Amidines: Mild Conditions for the Synthesis of 2-Fluoroalkyl Imidazole Derivatives[J]. Org. Lett.,2012,14(4):1130-1133.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[李珊]'s Articles
[李正珂]'s Articles
[袁亚芬]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[李珊]‘s Articles
[李正珂]‘s Articles
[袁亚芬]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2012186.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace