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学科主题: 氟化学
题名: Reactions of Sulfur- and Phosphorus-Substituted Fluoroalkylating Silicon Reagents with Imines and Enamines under Acidic Conditions
其他题名: 硫和磷取代的氟烷基硅试剂在酸性条件下与亚胺和烯胺的反应
作者: Kosobokov, M. D. ; Dilamn, A. D. ; Struchkova, M. I. ; Belyakov, P. A. ; Hu JB(胡金波)
通讯作者: Dilamn, A. D.
刊名: J. Org. Chem.
发表日期: 2012
卷: 77, 期:4, 页:2080-2086
收录类别: SCI
部门归属: 俄罗斯科学院有机化学研究所; 中科院上海有机化学研究所
英文摘要: Nucleophilic fluoroalkylation reactions of imines and enamines with alpha-phenylthio, alpha-phenylsulfonyl, and alpha-diethylphosphoryl substituted fluorinated silanes have been investigated. The reactions are promoted by hydrofluoric acid generated in situ from potassium hydrodifluoride and trifluoroacetic acid. Sulfur reagents worked well with both imines and enamines, whereas phosphorus reagent efficiently coupled only with enamines.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000300340000052
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28279
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Kosobokov, M. D.,Dilamn, A. D.,Struchkova, M. I.,et al. Reactions of Sulfur- and Phosphorus-Substituted Fluoroalkylating Silicon Reagents with Imines and Enamines under Acidic Conditions[J]. J. Org. Chem.,2012,77(4):2080-2086.
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