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学科主题: 氟化学
题名: Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature
其他题名: 铜参与的芳基硼酸和氟烷基碘在室温下的氧化氟烷基化反应
作者: Qi QQ(齐卿卿) ; Shen QL(沈其龙) ; Lv L(吕龙)
通讯作者: 沈其龙 ; 吕龙
刊名: J. Am. Chem. Soc.
发表日期: 2012
卷: 134, 期:15, 页:6548-6551
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A Cu-mediated ligandless aerobic fluoroalkylation of arylboronic acids under mild conditions is described for the first time. The reaction tolerates a wide range of functional groups, allowing for further transformation. Mechanistic studies suggest that [RfCu] is the active Cu species that forms the desired perfluoroalkylarenes and that [RfCu] is generated from [PhCu] by either an oxidative addition/reductive elimination mechanism or nucleophilic substitution via a halogen "ate" intermediate.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000302887300013
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28253
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Qi QQ,Shen QL,Lv L. Copper-Mediated Aerobic Fluoroalkylation of Arylboronic Acids with Fluoroalkyl Iodides at Room Temperature[J]. J. Am. Chem. Soc.,2012,134(15):6548-6551.
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