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学科主题: 氟化学
题名: Nucleophilic difluoromethylation of C=N bonds in heterocycles with difluoromethyl silane reagents
其他题名: 利用二氟甲基硅烷试剂对杂环化合物中的C=N键进行亲核二氟甲基化反应
作者: Huang WZ(黄维洲) ; Ni CF(倪传法) ; Zhao YC(赵延川) ; Zhang W(张伟) ; DILMAN ALEXANDER D ; Hu JB(胡金波)
通讯作者: 胡金波
刊名: Tetrahedron
发表日期: 2012
卷: 68, 期:26, 页:5137-5144
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 俄罗斯科学院有机化学研究所
英文摘要: An efficient and straightforward nucleophilic difluoromethylation of C=N bonds in heterocycles under the activation of alkylating agents has been developed. Cyclic iminium salts derived from dihydroisoquinolines, quinolines, and pyridines were successfully difluoromethylated with sulfur-based fluoroalkyl silanes affording a series of new difluoromethylated nitrogen-containing heterocyclic compounds. (C) 2012 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000305381700003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28231
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Huang WZ,Ni CF,Zhao YC,et al. Nucleophilic difluoromethylation of C=N bonds in heterocycles with difluoromethyl silane reagents[J]. Tetrahedron,2012,68(26):5137-5144.
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