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学科主题: 氟化学
题名: Reactions of 4-ethoxy-1,1,1-trifluorobut-3-en-2-one with diethyl malonate anion: synthesis and crystal structures of fluorinated organo alkali-metal complexes
其他题名: 三氟乙酰基乙烯基乙醚与丙二酸二乙酯的反应以及含氟有机碱金属配合物的晶体结构研究
作者: Song T(宋涛) ; Liu L(刘磊) ; Zhao JW(赵经纬) ; Jiang HL(蒋慧玲) ; Zhu SZ(朱仕正) ; Xu LZ(徐良忠)
通讯作者: 朱仕正
刊名: Tetrahedron
发表日期: 2012
卷: 68, 期:27-28, 页:5677-5682
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 青岛科技大学
英文摘要: At room temperature, 4-ethoxy-1,1,1-trifluorobut-3-en-2-one reacted with alkali metal salts of diethyl malonate to give two kinds of complexes. One is the solvent molecule-involved complexes, and the other is a sheer ion aggregates composed by alkali metal cation and carbanion. Both crystals are fully characterized by spectroscopic methods and single crystal X-ray diffraction analyses. (c) 2012 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000306350800044
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28229
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Song T,Liu L,Zhao JW,et al. Reactions of 4-ethoxy-1,1,1-trifluorobut-3-en-2-one with diethyl malonate anion: synthesis and crystal structures of fluorinated organo alkali-metal complexes[J]. Tetrahedron,2012,68(27-28):5677-5682.
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