SIOC OpenIR  > 中科院有机氟化学重点实验室
General and highly efficient fluorinated-N-heterocyclic carbene-based catalysts for the palladium-catalyzed Suzuki-Miyaura reaction
其他题名一种适用于钯催化Suzuki-Miyaura反应的广谱高效的氟化氮杂环卡宾催化剂
LIU TAOPING; ZHAO XIAOMING; Shen QL(沈其龙); Lv L(吕龙)
2012
发表期刊Tetrahedron
ISSN0040-4020
卷号68期号:32页码:6535-6547
摘要A general and highly efficient trifluoromethylated-N-heterocyclic carbene (NHC)-based catalyst for the palladium-catalyzed Suzuki-Miyaura reaction was reported. In the presence of the catalyst, reactions of non-activated aryl chlorides and triflates with aryl boronic acids occurred at room temperature with good to excellent yields (63-98%). In addition, catalysts generated from a combination of Pd(OAc)(2)/imidazolium salt 6a is not only effective for the coupling of heteroaryl boronic acid with aryl halides and heteroaryl halides, but also efficient for coupling of other heteroaryl halides and heteroaryl boronic acids. Finally, the catalyst is highly effective for Suzuki-Miyaura reaction of aryl bromides and chlorides with 0.01-0.1 mol % loading if the temperature was raised at refluxed THF/H2O. (C) 2012 Elsevier Ltd. All rights reserved.
学科领域氟化学
部门归属中科院上海有机化学研究所
URL查看原文
收录类别SCI
语种英语
WOS记录号WOS:000306267800019
引用统计
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/28225
专题中科院有机氟化学重点实验室
通讯作者Lv L(吕龙)
推荐引用方式
GB/T 7714
LIU TAOPING,ZHAO XIAOMING,Shen QL,et al. General and highly efficient fluorinated-N-heterocyclic carbene-based catalysts for the palladium-catalyzed Suzuki-Miyaura reaction[J]. Tetrahedron,2012,68(32):6535-6547.
APA LIU TAOPING,ZHAO XIAOMING,沈其龙,&吕龙.(2012).General and highly efficient fluorinated-N-heterocyclic carbene-based catalysts for the palladium-catalyzed Suzuki-Miyaura reaction.Tetrahedron,68(32),6535-6547.
MLA LIU TAOPING,et al."General and highly efficient fluorinated-N-heterocyclic carbene-based catalysts for the palladium-catalyzed Suzuki-Miyaura reaction".Tetrahedron 68.32(2012):6535-6547.
条目包含的文件
文件名称/大小 文献类型 版本类型 开放类型 使用许可
2012003.pdf(7489KB) 开放获取--请求全文
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[LIU TAOPING]的文章
[ZHAO XIAOMING]的文章
[沈其龙]的文章
百度学术
百度学术中相似的文章
[LIU TAOPING]的文章
[ZHAO XIAOMING]的文章
[沈其龙]的文章
必应学术
必应学术中相似的文章
[LIU TAOPING]的文章
[ZHAO XIAOMING]的文章
[沈其龙]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。