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学科主题: 氟化学 ; 金属有机化学
题名: Highly diastereoselective synthesis of quaternary alpha-trifluoromethyl alpha-amino acids by addition of benzylzinc reagents to chiral imines of trifluoropyruvate
其他题名: 通过苄基锌试剂对手性三氟丙酮酸酯亚胺高立体选择性加成合成具有季碳手心的a-氨基酸
作者: Yang J(杨洁) ; Min QQ(闵巧桥) ; HE YI ; Zhang XG(张新刚)
通讯作者: 张新刚
刊名: Tetrahedron Lett.
发表日期: 2011
卷: 52, 期:36, 页:4675-4677
收录类别: SCI
部门归属: 西南石油大学; 中科院上海有机化学研究所
英文摘要: An effective and facile method for highly diastereoselective synthesis of quaternary alpha-trifluoromethyl alpha-amino acids was developed in good yields with high diastereoselectivity (dr >20:1) via MgCl(2)-accelerated addition of benzylzinc reagents (Knochel type organozinc reagents) to (R)-phenylglycinol methyl ether based imines of trifluoropyruvate. (C) 2011 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000294145600022
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28219
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Yang J,Min QQ,HE YI,et al. Highly diastereoselective synthesis of quaternary alpha-trifluoromethyl alpha-amino acids by addition of benzylzinc reagents to chiral imines of trifluoropyruvate[J]. Tetrahedron Lett.,2011,52(36):4675-4677.
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