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学科主题: 氟化学 ; 金属有机化学
题名: Highly enantioselective zinc/BINOL-catalyzed alkynylation of alpha-ketoimine ester: a new entry to optically active quaternary alpha-CF(3) alpha-amino acids
其他题名: 锌(BINOL)催化下炔对a-酮酸酯亚胺的高立体选择性加成反应
作者: HUANG GAOCHAO ; Yang J(杨洁) ; Zhang XG(张新刚)
通讯作者: 张新刚
刊名: Chem. Commun.
发表日期: 2011-01-01
卷: 47, 期:19, 页:5587-5589
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 西南石油大学
英文摘要: An effective method for highly enantioselective alkynylation of ketoimine (alpha-trifluoromethyl ketoimine ester) has been developed via a zinc/BINOL catalyzed process. This protocol provides a useful and facile access to optically active quaternary alpha-trifluoromethyl alpha-amino acids and related derivatives of interest in life sciences.
语种: 英语
相关网址: 查看原文
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28217
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
HUANG GAOCHAO,Yang J,Zhang XG. Highly enantioselective zinc/BINOL-catalyzed alkynylation of alpha-ketoimine ester: a new entry to optically active quaternary alpha-CF(3) alpha-amino acids[J]. Chem. Commun.,2011,47(19):5587-5589.
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