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学科主题: 氟化学 ; 金属有机化学
题名: Highly diastereoselective synthesis of quaternary alpha-trifluoromethyl alpha-amino acids from chiral imines of trifluoropyruvate
其他题名: 基于手性三氟丙酮酸酯亚胺高立体选择性合成alpha-三氟甲基-alpha-氨基酸
作者: Min QQ(闵巧桥) ; He CY(贺春阳) ; Zhou HB(周海滨) ; Zhang XG(张新刚)
通讯作者: 张新刚
刊名: Chem. Commun.
发表日期: 2010
卷: 46, 期:42, 页:8029-8031
收录类别: SCI
部门归属: 中国科学院上海有机化学研究所; 武汉大学
英文摘要: An efficient method for highly diastereoselective synthesis of quaternary alpha-trifluoromethyl alpha-amino acids was developed via indium mediated allylation of (R)-phenylglycinol methyl ether based imines of trifluoropyruvate in good yields with high diastereoselectivities at room temperature; to illustrate the application of this method in organic synthesis, 2-allyl-2-(trifluoromethyl) aziridine was prepared in an efficient manner.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000283260400049
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28203
Appears in Collections:中科院有机氟化学重点实验室_期刊论文

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Recommended Citation:
Min QQ,He CY,Zhou HB,et al. Highly diastereoselective synthesis of quaternary alpha-trifluoromethyl alpha-amino acids from chiral imines of trifluoropyruvate[J]. Chem. Commun.,2010,46(42):8029-8031.
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