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学科主题: 金属有机化学
题名: Highly enantioselective asymmetric hydrogenation of (E)-beta,beta-disubstituted alpha,beta-unsaturated Weinreb amides catalyzed by Ir(I) complexes of SpinPhox ligands
其他题名: SpinPhox/Ir(I)络合物催化高对映选择性不对称氢化合成Weinreb酰胺
作者: Shang J(商健) ; Han ZB(韩召斌) ; Li Y(李洋) ; Wang Z(王正) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Chem. Commun.
发表日期: 2012
卷: 48, 期:42, 页:5172-5174
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: The Ir(I) complexes of chiral spiro phosphino-oxazoline ligands (SpinPhox) have demonstrated good to excellent enantioselectivity in the asymmetric hydrogenation (AH) of a variety of (E)-beta,beta-disubstituted alpha,beta-unsaturated N-methoxy-N-methylamides, affording the corresponding optically active Weinreb amides with up to 97% ee.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000303320000042
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28201
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Shang J,Han ZB,Li Y,et al. Highly enantioselective asymmetric hydrogenation of (E)-beta,beta-disubstituted alpha,beta-unsaturated Weinreb amides catalyzed by Ir(I) complexes of SpinPhox ligands[J]. Chem. Commun.,2012,48(42):5172-5174.
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