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学科主题: 金属有机化学
题名: Facile Synthesis of Fully Substituted Dihydro-beta-carbolines via Bronsted Acid Promoted Cascade Reactions of alpha-Indolyl Propargylic Alcohols with Nitrones
其他题名: 通过布朗斯特酸促进的α-吲哚基炔丙醇与硝酮的串联反应简便合成全取代二氢-β-咔啉
作者: Wang L(王璐) ; Xie X(谢鑫) ; Liu YH(刘元红)
通讯作者: 刘元红
刊名: Org. Lett.
发表日期: 2012
卷: 14, 期:23, 页:5848-5851
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A straightforward synthesis of fully substituted beta-carbolines via Bronsted acid promoted cyclizations of alpha-indolyl propargylic alcohols with nitrones is described. The use of nitrones bearing alkenyl or electron-rich aryl groups as the R-4 substituent dramatically switches the reaction pathway to afford tetrasubstituted alkenes and amines, which is assumed to proceed through a rearrangement reaction involving N-O bond cleavage and 1,2-migration of the R-4 group to an adjacent nitrogen atom,
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000311926000010
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28197
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wang L,Xie X,Liu YH. Facile Synthesis of Fully Substituted Dihydro-beta-carbolines via Bronsted Acid Promoted Cascade Reactions of alpha-Indolyl Propargylic Alcohols with Nitrones[J]. Org. Lett.,2012,14(23):5848-5851.
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