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学科主题: 金属有机化学
题名: Diastereoselective and Enantioselective Desymmetrization of alpha-Substituted Cyclohexadienones via Intramolecular Stetter Reaction
其他题名: 通过分子内Stetter反应对α-取代的环己二酮的非对映选择性和不对称去对称化
作者: Jia MQ(贾敏强) ; Liu C(刘川) ; You SL(游书力)
通讯作者: 游书力
刊名: J. Org. Chem.
发表日期: 2012
卷: 77, 期:23, 页:10996-11001
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: Highly diastereoselective and enantioselective desymmetrization of alpha-substituted cyclohexadienones via NHC-catalyzed intramolecular Stetter reaction was realized. Amino-indanol derived triazolium salt bearing a C6F5 group was found to be the optimal catalyst precursor in the intramolecular Stetter reaction furnishing tricyclic products bearing multi-stereocenters in up to 96% yield and >99% ee.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000311926100060
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28195
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Jia MQ,Liu C,You SL. Diastereoselective and Enantioselective Desymmetrization of alpha-Substituted Cyclohexadienones via Intramolecular Stetter Reaction[J]. J. Org. Chem.,2012,77(23):10996-11001.
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