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学科主题: 金属有机化学
题名: One-Pot Synthesis of Pyrrolo[1,2-a]indoles by Chiral N-Triflyl Phosphoramide Catalyzed Friedel-Crafts Alkylation of 4,7-Dihydroindole with beta,gamma-Unsaturated alpha-Keto Esters
其他题名: 通过手性磷酰胺催化的4,7-二氢吲哚与β,γ-不饱和 α-酮酸酯的Friedel-Crafts烷基化实现的吡咯[1,2-a]吲哚的一锅法合成
作者: Ceng M(曾蜜) ; Zhang W(张玮) ; You SL(游书力)
通讯作者: 张玮 ; 游书力
刊名: Chin. J. Chem.
发表日期: 2012
卷: 30, 期:11, 页:2615-2623
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: Chiral N-triflyl phosphoramide was found an efficient catalyst for the enantioselective Friedel-Crafts alkylation reaction of 4,7-dihydroindole with beta,gamma-unsaturated alpha-keto esters. In the presence of 5 mol% of the optimized catalyst, various pyrrolo[1,2-a]indoles were obtained in excellent enantioselectivity, moderate yields and up to 3:1 diastereoselectivity based on the one-pot synthesis including the Friedel-Crafts alkylation reaction and the subsequent p-benzoquinone oxidation.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000311169300005
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28181
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ceng M,Zhang W,You SL. One-Pot Synthesis of Pyrrolo[1,2-a]indoles by Chiral N-Triflyl Phosphoramide Catalyzed Friedel-Crafts Alkylation of 4,7-Dihydroindole with beta,gamma-Unsaturated alpha-Keto Esters[J]. Chin. J. Chem.,2012,30(11):2615-2623.
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