中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-vinylidenecyclopropanes with Carbon Monoxide (CO)
其他题名: Rh(I)催化的亚乙烯基环丙烷-烯烃的P-K反应
作者: Yuan W(袁渭) ; Dong X(董翔) ; Shi M(施敏) ; Patrick McDowell ; Li GG(李桂根)
通讯作者: 施敏 ; 李桂根
刊名: Org. Lett.
发表日期: 2012
卷: 14, 期:21, 页:5582-5585
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 南京大学; Texas Tech Univ
英文摘要: An intramolecular Pauson-Khand type cycloaddition reaction of ene-vinylidenecyclopropanes with carbon monoxide has been established by using [Rh(COD)Cl](2) as the catalyst. The reaction was found to be highly efficient in solvents of 1,2-dichloroethane and 1,1,2,2-tetrachloroethane to give excellent yields of 90-99%. The reaction provides easy access to a series of fused 6,5-ring structures containing spiro-cyclopropane units that are useful for drug design and development. A mechanism of this cycloaddition process has been proposed accounting for structures of resulting products that were unambiguously assigned by X-ray diffractional analysis.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000311245600051
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28177
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2012565.pdf(455KB)----开放获取--View Download

Recommended Citation:
Yuan W,Dong X,Shi M,et al. Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-vinylidenecyclopropanes with Carbon Monoxide (CO)[J]. Org. Lett.,2012,14(21):5582-5585.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[袁渭]'s Articles
[董翔]'s Articles
[施敏]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[袁渭]‘s Articles
[董翔]‘s Articles
[施敏]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2012565.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace