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Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-vinylidenecyclopropanes with Carbon Monoxide (CO)
其他题名Rh(I)催化的亚乙烯基环丙烷-烯烃的P-K反应
Yuan W(袁渭); Dong X(董翔); Shi M(施敏); Patrick McDowell; Li GG(李桂根)
2012
发表期刊Org. Lett.
ISSN1523-7060
卷号14期号:21页码:5582-5585
摘要An intramolecular Pauson-Khand type cycloaddition reaction of ene-vinylidenecyclopropanes with carbon monoxide has been established by using [Rh(COD)Cl](2) as the catalyst. The reaction was found to be highly efficient in solvents of 1,2-dichloroethane and 1,1,2,2-tetrachloroethane to give excellent yields of 90-99%. The reaction provides easy access to a series of fused 6,5-ring structures containing spiro-cyclopropane units that are useful for drug design and development. A mechanism of this cycloaddition process has been proposed accounting for structures of resulting products that were unambiguously assigned by X-ray diffractional analysis.
学科领域金属有机化学
部门归属中科院上海有机化学研究所; 南京大学; Texas Tech Univ
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收录类别SCI
语种英语
WOS记录号WOS:000311245600051
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被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/28177
专题金属有机化学国家重点实验室
通讯作者Shi M(施敏); Li GG(李桂根)
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GB/T 7714
Yuan W,Dong X,Shi M,et al. Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-vinylidenecyclopropanes with Carbon Monoxide (CO)[J]. Org. Lett.,2012,14(21):5582-5585.
APA 袁渭,董翔,施敏,Patrick McDowell,&李桂根.(2012).Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-vinylidenecyclopropanes with Carbon Monoxide (CO).Org. Lett.,14(21),5582-5585.
MLA 袁渭,et al."Rh(I)-catalyzed Pauson-Khand-type Cycloaddition Reaction of Ene-vinylidenecyclopropanes with Carbon Monoxide (CO)".Org. Lett. 14.21(2012):5582-5585.
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