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学科主题: 金属有机化学 ; 氟化学
题名: Asymmetric [3+2] Cycloaddition of Azomethine Ylides Catalyzed by Silver(I) Triflate with a Chiral Bipyrrolidine-Derived Phosphine Ligand
其他题名: 联吡咯衍生膦络合物三氟甲磺酸银催化的亚胺叶立德不对称3加2环加成反应
作者: Gu X(顾昕) ; Xu ZJ(徐镇江) ; Lu JY(卢嘉茵) ; Zhi ZM(支志明)
通讯作者: 徐镇江 ; 支志明
刊名: Synthesis
发表日期: 2012-01-01
卷: 44, 期:21, 页:3307-3314
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 香港大学
英文摘要: Two novel chiral bipyrrolidine-derived phosphine ligands L1 and L2 were synthesized. The 'AgOTf+L1' protocol catalyzes the asymmetric [3+2] cycloaddition of azomethine ylides with alkenes to give highly substituted pyrrolidines in good yields (up to 90%) with moderate to high diastereoselectivities (up to > 19:1 dr) and enantioselectivities (up to 76%).
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000310461400011
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28167
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Gu X,Xu ZJ,Lu JY,et al. Asymmetric [3+2] Cycloaddition of Azomethine Ylides Catalyzed by Silver(I) Triflate with a Chiral Bipyrrolidine-Derived Phosphine Ligand[J]. Synthesis,2012,44(21):3307-3314.
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