中国科学院上海有机化学研究所机构知识库
Advanced  
SIOC OpenIR  > 金属有机化学国家重点实验室  > 期刊论文
学科主题: 金属有机化学
题名: Synthesis, Structure and Ethylene Polymerization Behavior of Group 4 Metal Complexes Bearing Salicylaldaminato Ligands with Appended Donor Functionality
其他题名: 边臂修饰的水杨醛亚胺第四族金属配合物的合成、结构及其乙烯聚合行为研究
作者: Wang XK(王新科) ; SIT METMET ; Sun J(孙杰) ; Tang Y(唐勇) ; Xie ZW(谢作伟)
通讯作者: 唐勇 ; 谢作伟
刊名: 化学学报
发表日期: 2012
卷: 70, 期:18, 页:1909-1916
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 香港中文大学
英文摘要: A series of group 4 metal complexes were synthesized by an equimolar reaction of M(CH2Ph)(4) with (E)-2,4-di-tert-butyl-6-[(phenylimino)methyl]phenol bearing donor functionality. This process involved toluene elimination followed by an intramolecular migration reaction of one benzyl group from metal to the imino carbon, which was supported by the isolation and structural characterization of the intermediate. These new complexes were fully characterized by multinuclear NMR spectroscopy, elemental analyses and X-ray analyses. The titanium complexes showed a very high activity in both ethylene polymerization and ethylene/1-hexene copolymerization upon activation with modified methylaluminoxane (MMAO), whereas the corresponding zirconium and hafnium complexes were almost inactive under the same reaction conditions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000310255500004
Citation statistics:
内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28155
Appears in Collections:金属有机化学国家重点实验室_期刊论文

Files in This Item: Download All
File Name/ File Size Content Type Version Access License
2012523.pdf(805KB)----开放获取--View Download

Recommended Citation:
Wang XK,SIT METMET,Sun J,et al. Synthesis, Structure and Ethylene Polymerization Behavior of Group 4 Metal Complexes Bearing Salicylaldaminato Ligands with Appended Donor Functionality[J]. 化学学报,2012,70(18):1909-1916.
Service
Recommend this item
Sava as my favorate item
Show this item's statistics
Export Endnote File
Google Scholar
Similar articles in Google Scholar
[王新科]'s Articles
[SIT METMET]'s Articles
[孙杰]'s Articles
CSDL cross search
Similar articles in CSDL Cross Search
[王新科]‘s Articles
[SIT METMET]‘s Articles
[孙杰]‘s Articles
Related Copyright Policies
Null
Social Bookmarking
Add to CiteULike Add to Connotea Add to Del.icio.us Add to Digg Add to Reddit
文件名: 2012523.pdf
格式: Adobe PDF
此文件暂不支持浏览
所有评论 (0)
暂无评论
 
评注功能仅针对注册用户开放,请您登录
您对该条目有什么异议,请填写以下表单,管理员会尽快联系您。
内 容:
Email:  *
单位:
验证码:   刷新
您在IR的使用过程中有什么好的想法或者建议可以反馈给我们。
标 题:
 *
内 容:
Email:  *
验证码:   刷新

Items in IR are protected by copyright, with all rights reserved, unless otherwise indicated.

 

 

Valid XHTML 1.0!
Powered by CSpace