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学科主题: 金属有机化学
题名: Palladium(II)-Catalyzed Cyclization Reaction of 2-(Alk-2 '-ynyloxy)benzonitriles or 2-(Alk-2 '-ynylamino)benzonitriles: A Facile Way to 2H-Chromene and 1,2-Dihydroquinoline Derivatives
其他题名: 钯(II)催化的2-(炔-2'-氧基)苯腈或2-(炔-2'-胺基)苯腈的环化反应: 2H-苯并吡喃和1,2-二氢喹啉衍生物的简易合成
作者: Xia GQ(夏国钦) ; Han XL(韩秀玲) ; Lu XY(陆熙炎)
通讯作者: 韩秀玲 ; 陆熙炎
刊名: Adv. Synth. Catal.
发表日期: 2012
卷: 354, 期:14-15, 页:2701-2705
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: An efficient synthesis of 2H-chromenes and 1,2-dihydroquinolines from palladium(II)-catalyzed tandem reactions of 2-(alk-2'-ynyloxy)benzonitriles or 2-(alk-2'-ynylamino)benzonitriles was developed. This tandem reaction involves an intermolecular trans-acetoxypalladation of an alkyne followed by an addition to the nitrile group to quench the carbon-palladium bond and complete the catalytic cycle without the necessity of a redox system.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000309907300017
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28151
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Xia GQ,Han XL,Lu XY. Palladium(II)-Catalyzed Cyclization Reaction of 2-(Alk-2 '-ynyloxy)benzonitriles or 2-(Alk-2 '-ynylamino)benzonitriles: A Facile Way to 2H-Chromene and 1,2-Dihydroquinoline Derivatives[J]. Adv. Synth. Catal.,2012,354(14-15):2701-2705.
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