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学科主题: 金属有机化学
题名: Dinuclear Iron Complex-Catalyzed Cross-Coupling of Primary Alkyl Fluorides with Aryl Grignard Reagents
其他题名: 铁催化的C(sp3)-F键的芳基化反应
作者: Mo ZB(莫贞波) ; Zhang Q(张强) ; Deng L(邓亮)
通讯作者: 邓亮
刊名: Organometallics
发表日期: 2012
卷: 31, 期:18, 页:6518-6521
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: Iron-catalyzed cross-coupling of nonactivated primary alkyl fluorides with aryl Grignard reagents has been achieved by using the low-coordinate dinuclear iron complex [(IPr2Me2)Fe(mu(2)-NDipp)(2)Fe(IPr2Me2)] as the catalyst. This iron-catalyzed C(sp(3))-F bond arylation reaction is applicable to a variety of aryl Grignard reagents and primary alkyl fluorides. The product pattern suggests the involvement of a radical-type mechanism for its C-F bond scission step.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000309022700003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28129
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Mo ZB,Zhang Q,Deng L. Dinuclear Iron Complex-Catalyzed Cross-Coupling of Primary Alkyl Fluorides with Aryl Grignard Reagents[J]. Organometallics,2012,31(18):6518-6521.
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