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学科主题: 金属有机化学
题名: CuCl-K2CO3-catalyzed highly selective borylcupration of internal alkynes - ligand effect
其他题名: CuCl-K2CO3催化的高选择性的内炔的硼化反应及其配体效应
作者: Yuan WM(袁伟明) ; Ma SM(麻生明)
通讯作者: 麻生明
刊名: Org. Biomol. Chem.
发表日期: 2012
卷: 10, 期:36, 页:7266-7268
收录类别: SCI
部门归属: 华东师范大学; 中科院上海有机化学研究所
英文摘要: An efficient and practical copper-catalyzed highly regio- and stereoselective borylcupration of internal alkynes with bis(pinacolato) diboron using a catalytic amount of K2CO3 as base producing Z-alkenylboron compounds has been demonstrated by applying the ligand effect: commercially available electron-rich tris(p-methoxyphenyl) phosphine ensures a smooth and efficient reaction. Functionalized alkynes, such as propargylic alcohols and derivatives as well as N-propargyl tosylamide, may also be used with excellent selectivity.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000307790600003
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28121
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Yuan WM,Ma SM. CuCl-K2CO3-catalyzed highly selective borylcupration of internal alkynes - ligand effect[J]. Org. Biomol. Chem.,2012,10(36):7266-7268.
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