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学科主题: 金属有机化学
题名: Rh(I)-Catalyzed Enantioselective Hydrogenation of alpha-Substituted Ethenylphosphonic Adds
其他题名: Rh(I)催化α-取代乙烯基膦酸的不对称氢化
作者: Dong KW(董开武) ; Wang Z(王正) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: J. Am. Chem. Soc.
发表日期: 2012
卷: 134, 期:30, 页:12474-12477
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A class of chiral Rh(I) catalysts containing monodentate phosphorous acid diesters tautomerized from the corresponding secondary phosphine oxides was discovered by serendipitous hydrolysis of phosphoramidite ligands. The evolved catalysts demonstrated unprecedented enantioselectivities (98-99% cc) and high catalytic activities (as low as 0.01 mol% catalyst loading) in asymmetric hydrogenations of a wide variety of alpha-aryl-/alkyl-substituted ethenylphosphonic acids, providing a facile approach to the corresponding enantiopure phosphonic acids with significant biological importance.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000306942600038
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28111
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Dong KW,Wang Z,Ding KL. Rh(I)-Catalyzed Enantioselective Hydrogenation of alpha-Substituted Ethenylphosphonic Adds[J]. J. Am. Chem. Soc.,2012,134(30):12474-12477.
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