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学科主题: 金属有机化学
题名: Rh(I)/DpenPhos catalyzed asymmetric hydrogenation of enol esters and potassium (E)-3-cyano-5-methylhex-3-enoate
其他题名: Rh/DpenPhos催化烯醇酯以及(E)-3-氰基-5-甲基-3-己烯酸钾盐的不对称氢化
作者: Liu Y(刘龑) ; Wang Z(王正) ; Ding KL(丁奎岭)
通讯作者: 丁奎岭
刊名: Tetrahedron
发表日期: 2012
卷: 68, 期:37, 页:7581-7585
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: Rh(I) complexes of a class of modular chiral monodentate phosphoramidites were highly efficient for the asymmetric hydrogenation of enol esters bearing alpha-aryl or alpha-alkyl groups, to afford the corresponding hydrogenation products in high enantioselectivities (87-95% ee) and reactivities (turnover number up to 10,000). These ligands were also shown to be effective in Rh(I)-catalyzed asymmetric hydrogenation of the potassium salt of (E)-3-cyano-5-methylhex-3-enoate, to give the corresponding product (a precursor to CI-1008) with up to 95% ee and complete conversion of substrate. (C) 2012 Elsevier Ltd. All rights reserved.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000307802300008
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28097
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Liu Y,Wang Z,Ding KL. Rh(I)/DpenPhos catalyzed asymmetric hydrogenation of enol esters and potassium (E)-3-cyano-5-methylhex-3-enoate[J]. Tetrahedron,2012,68(37):7581-7585.
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