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学科主题: 金属有机化学
题名: Asymmetric dearomatization of pyrroles via Ir-catalyzed allylic substitution reaction: enantioselective synthesis of spiro-2H-pyrroles
其他题名: 通过铱催化的烯丙基取代反应实现的吡咯的不对称去芳构化: 螺2H-吡咯的不对称合成
作者: Zhuo CX(卓春祥) ; Liu WB(刘文博) ; Wu QF(武庆锋) ; You SL(游书力)
通讯作者: 游书力
刊名: Chem. Sci.
发表日期: 2012
卷: 3, 期:1, 页:205-208
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: Asymmetric dearomatization of pyrroles has been accomplished by using Ir-catalyzed intramolecular asymmetric allylic alkylation reactions. Reactions of allylic carbonate tethered pyrroles in the presence of [Ir(cod)Cl](2) and a BINOL-derived phosphoramidite ligand lead to efficient generation of spiro-2H-pyrrole derivatives with up to 96% ee.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000297473200028
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28095
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Zhuo CX,Liu WB,Wu QF,et al. Asymmetric dearomatization of pyrroles via Ir-catalyzed allylic substitution reaction: enantioselective synthesis of spiro-2H-pyrroles[J]. Chem. Sci.,2012,3(1):205-208.
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