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学科主题: 金属有机化学
题名: Rh-catalyzed intramolecular sp(2) C-H bond difluoromethylenation
其他题名: 铑催化的分子内Sp(2)C-H键的二氟甲基化反应
作者: Li YJ(力亚军) ; Zhu JT(祝江涛) ; Xie HB(谢海波) ; Li S(李珊) ; Peng DJ(彭东杰) ; Li ZK(李正珂) ; Wu YM(吴永明) ; Gong YF(龚跃发)
通讯作者: 吴永明 ; 龚跃发
刊名: Chem. Commun.
发表日期: 2012
卷: 48, 期:25, 页:3136-3138
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 华中科技大学
英文摘要: A new Rh-catalyzed intramolecular coupling reaction of a CF2Br group with a 2-aryl of indole or pyrrole via C-H bond activation is presented. This reaction represents a new way of incorporating difluoromethylene groups into organic compounds. Preliminary mechanistic studies suggest that this reaction might not occur via a conventional free radical pathway.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000300782600030
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28073
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Li YJ,Zhu JT,Xie HB,et al. Rh-catalyzed intramolecular sp(2) C-H bond difluoromethylenation[J]. Chem. Commun.,2012,48(25):3136-3138.
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