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学科主题: 金属有机化学
题名: Enantioselective synthesis of fluorene derivatives by chiral N-triflyl phosphoramide catalyzed double Friedel-Crafts alkylation reaction
其他题名: 通过N-磷酰胺催化的双Friedel–Crafts烷基化反应实现的芴衍生物的手性合成
作者: Wang SG(王守国) ; Han L(韩龙) ; Ceng M(曾蜜) ; Sun FL(孙丰来) ; Zhang W(张玮) ; You SL(游书力)
通讯作者: 游书力
刊名: Org. Biomol. Chem.
发表日期: 2012
卷: 10, 期:16, 页:3202-3209
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A highly efficient tandem double Friedel-Crafts reaction between indoles and 2-formylbiphenyl derivatives by chiral N-triflyl phosphoramide was realized. Under mild conditions, various 9-(3-indolyl) fluorene derivatives have been obtained in good yield and up to 94% ee. Comparing to their corresponding chiral phosphoric acids, chiral N-triflyl phosphoramides catalyzed reactions led to products with opposite absolute configuration.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000302028800012
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28067
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Wang SG,Han L,Ceng M,et al. Enantioselective synthesis of fluorene derivatives by chiral N-triflyl phosphoramide catalyzed double Friedel-Crafts alkylation reaction[J]. Org. Biomol. Chem.,2012,10(16):3202-3209.
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