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学科主题: 金属有机化学
题名: Ni(0) or Cu(0) catalyzed cleavage of the unactivated C-Cl bond of 2-chloro-1,1,1-trifluoroethane (HCFC-133a) via a single electron transfer (SET) process
其他题名: 零价镍或零价铜催化F-133a的C-Cl断裂的单电子转移反应
作者: Tang XJ(唐小军) ; Chen QY(陈庆云)
通讯作者: 陈庆云
刊名: Chem. Sci.
发表日期: 2012
卷: 3, 期:5, 页:1694-1697
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: The reductive cleavage of the unactivated carbon-chlorine bond of 2-chloro-1,1,1-trifluoroethane (HCFC-133a) via a single electron transfer (SET) process using transition-metal-catalysis has been achieved. Ni(0) or Cu(0) catalytic systems afford 1,1,1-trifluoroethane (HFC-143a) or 1,1-difluoroethylene (VDF) with excellent yields respectively. The formation of VDF may be due to the beta-elimination of the 1,1,1-trifluoroethyl anion generated by SET between the corresponding radical and a Cu(I) intermediate.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000302319000046
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28057
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Tang XJ,Chen QY. Ni(0) or Cu(0) catalyzed cleavage of the unactivated C-Cl bond of 2-chloro-1,1,1-trifluoroethane (HCFC-133a) via a single electron transfer (SET) process[J]. Chem. Sci.,2012,3(5):1694-1697.
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