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学科主题: 金属有机化学
题名: Enantioselective synthesis of 2,5-dihydrobenzo[b]azepine derivatives via iridium-catalyzed asymmetric allylic amination with 2-allylanilines and ring-closing-metathesis reaction
其他题名: 通过铱催化的2-烯丙基苯胺的不对称烯丙基胺化和关环复分解(RCM)实现的2,5-dihydrobenzo[b]azepine衍生物的手性合成
作者: Ye KY(叶克印) ; Dai LX(戴立信) ; You SL(游书力)
通讯作者: 游书力
刊名: Org. Biomol. Chem.
发表日期: 2012
卷: 10, 期:30, 页:5932-5939
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: Iridium-catalyzed asymmetric allylic amination of allylic carbonates with 2-allylanilines was realized. With a catalyst generated from 2 mol% of [Ir(dbcot)Cl](2) (dbcot = dibenzo[a,e]cyclooctatetraene) and 4 mol% of phosphoramidite ligand (L3), the amination products were obtained in up to 99% yield and 99% ee. Subjecting amination products to trifluoroacetyl protection and ring-closing-metathesis reaction provided an efficient synthesis of enantioenriched 2,5-dihydrobenzo[b]azepine derivatives.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000306276800040
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28045
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Ye KY,Dai LX,You SL. Enantioselective synthesis of 2,5-dihydrobenzo[b]azepine derivatives via iridium-catalyzed asymmetric allylic amination with 2-allylanilines and ring-closing-metathesis reaction[J]. Org. Biomol. Chem.,2012,10(30):5932-5939.
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