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学科主题: 金属有机化学
题名: Diastereo- and Enantioselective Synthesis of Fluorinated Proline Derivatives via Copper(I)-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition
其他题名: 铜催化不对称1,3-偶极环加成反应非对映选择性及对映选择性合成氟代脯氨酸衍生物
作者: Li Q(李青) ; Ding CH(丁昌华) ; Li XH(李小惠) ; WEISSENSTEINER WALTER ; Hou XL(侯雪龙)
通讯作者: 侯雪龙
刊名: Synthesis
发表日期: 2012
卷: 44, 期:2, 页:265-271
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 奥地利维也纳大学
英文摘要: A catalytic asymmetric cycloaddition reaction of fluoromethyl-substituted nitroalkenes with azomethine ylides was developed using a catalyst derived from copper(I) perchlorate and a commercially available, chiral Walphos ligand. This method provides a simple approach to optically active exo-3-(fluoromethyl)proline derivatives in high yields, as well as in high diastereo and enantioselectivities.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000300198400014
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28035
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Li Q,Ding CH,Li XH,et al. Diastereo- and Enantioselective Synthesis of Fluorinated Proline Derivatives via Copper(I)-Catalyzed Asymmetric 1,3-Dipolar Cycloaddition[J]. Synthesis,2012,44(2):265-271.
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