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学科主题: 金属有机化学
题名: Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature
其他题名: 室温下钯催化活性烯烃的氧化芳基烷基化反应
作者: Mu X(慕欣) ; Wu T(吴涛) ; Wang HY(王昊阳) ; Guo YL(郭寅龙) ; Liu GS(刘国胜)
通讯作者: 刘国胜
刊名: J. Am. Chem. Soc.
发表日期: 2012
卷: 134, 期:2, 页:878-881
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A palladium-catalyzed intramolecular oxidative aryltrifluoromethylation reaction of activated alkenes has been explored. The reaction allows for an efficient synthesis of a variety of CF3-containing oxindoles. Preliminary mechanistic study indicated that the reaction involves a C-sp(3)-Pd-IV(CF3) intermediate, which undergoes reductive elimination to afford a C-sp(3)-CF3 bond.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000301084300035
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28033
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Mu X,Wu T,Wang HY,et al. Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature[J]. J. Am. Chem. Soc.,2012,134(2):878-881.
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