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学科主题: 金属有机化学
题名: Highly Efficient Synthesis of cis-[3]Cumulenic Diols via Zirconocene-Mediated Coupling of 1,3-Butadiynes with Aldehydes
其他题名: 利用茂锆促进的1,3-丁二炔与醛的偶联反应高效合成顺式[3]联烯二醇
作者: Fu XP(付晓平) ; Yu SS(俞莎莎) ; Fan GQ(范国钦) ; Liu YH(刘元红) ; Li YX(李玉学)
通讯作者: 刘元红 ; 李玉学
刊名: Organometallics
发表日期: 2012
卷: 31, 期:2, 页:531-534
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A highly efficient and convenient method for the monozirconation of silyl- or tert-butyl-substituted 1,3-butadiynes using the Negishi reagent has been developed. The resulting zirconium butadiyne complexes undergo two syn-S(E)2' reactions with various aldehydes to yield the cis-[3]cumulenic diols with moderate to high diastereoselectivities. The silyl substituents at the butadiyne terminus show remarkable influence on the diastereoselectivity.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000299351500005
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28031
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Fu XP,Yu SS,Fan GQ,et al. Highly Efficient Synthesis of cis-[3]Cumulenic Diols via Zirconocene-Mediated Coupling of 1,3-Butadiynes with Aldehydes[J]. Organometallics,2012,31(2):531-534.
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