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学科主题: 金属有机化学
题名: Enatioselective Synthesis of Highly Functionalized Trifluoromethyl-Bearing Cyclopentenes: Asymmetric [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Trifluoroethylidenemalonates Catalyzed by Multifunctional Thiourea-Phosphines
其他题名: 对映选择性地制备含有三氟甲基的官能团化环戊烯: 膦和硫脲多官能团手性膦催化的MBH加成产物和含三氟烯烃的不对称[3+2]环加成反应
作者: Deng HP(邓红平) ; Wei Y(魏音) ; Shi M(施敏)
通讯作者: 施敏
刊名: Adv. Synth. Catal.
发表日期: 2012
卷: 354, 期:5, 页:783-789
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: On the basis of the design and synthesis of multifunctional thiourea-phosphines, a catalytic method for the asymmetric [3+2]?annulation of MoritaBaylisHillman carbonates with trifluoroethylidenemalonates has been developed, affording highly functionalized trifluoromethyl-bearing cyclopentenes in excellent yields, high diastereoselectivities and enantioselectivities under mild conditions.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000301777500004
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28019
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Deng HP,Wei Y,Shi M. Enatioselective Synthesis of Highly Functionalized Trifluoromethyl-Bearing Cyclopentenes: Asymmetric [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Trifluoroethylidenemalonates Catalyzed by Multifunctional Thiourea-Phosphines[J]. Adv. Synth. Catal.,2012,354(5):783-789.
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