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Enatioselective Synthesis of Highly Functionalized Trifluoromethyl-Bearing Cyclopentenes: Asymmetric [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Trifluoroethylidenemalonates Catalyzed by Multifunctional Thiourea-Phosphines
其他题名对映选择性地制备含有三氟甲基的官能团化环戊烯: 膦和硫脲多官能团手性膦催化的MBH加成产物和含三氟烯烃的不对称[3+2]环加成反应
Deng HP(邓红平); Wei Y(魏音); Shi M(施敏)
2012
发表期刊Adv. Synth. Catal.
ISSN1615-4150
卷号354期号:5页码:783-789
摘要On the basis of the design and synthesis of multifunctional thiourea-phosphines, a catalytic method for the asymmetric [3+2]?annulation of MoritaBaylisHillman carbonates with trifluoroethylidenemalonates has been developed, affording highly functionalized trifluoromethyl-bearing cyclopentenes in excellent yields, high diastereoselectivities and enantioselectivities under mild conditions.
学科领域金属有机化学
部门归属中科院上海有机化学研究所
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收录类别SCI
语种英语
WOS记录号WOS:000301777500004
引用统计
被引频次:65[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.sioc.ac.cn/handle/331003/28019
专题金属有机化学国家重点实验室
通讯作者Shi M(施敏)
推荐引用方式
GB/T 7714
Deng HP,Wei Y,Shi M. Enatioselective Synthesis of Highly Functionalized Trifluoromethyl-Bearing Cyclopentenes: Asymmetric [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Trifluoroethylidenemalonates Catalyzed by Multifunctional Thiourea-Phosphines[J]. Adv. Synth. Catal.,2012,354(5):783-789.
APA 邓红平,魏音,&施敏.(2012).Enatioselective Synthesis of Highly Functionalized Trifluoromethyl-Bearing Cyclopentenes: Asymmetric [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Trifluoroethylidenemalonates Catalyzed by Multifunctional Thiourea-Phosphines.Adv. Synth. Catal.,354(5),783-789.
MLA 邓红平,et al."Enatioselective Synthesis of Highly Functionalized Trifluoromethyl-Bearing Cyclopentenes: Asymmetric [3+2] Annulation of Morita-Baylis-Hillman Carbonates with Trifluoroethylidenemalonates Catalyzed by Multifunctional Thiourea-Phosphines".Adv. Synth. Catal. 354.5(2012):783-789.
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