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学科主题: 金属有机化学
题名: Iridium-Catalyzed Allylic Alkylation Reaction with N-Aryl Phosphoramidite Ligands: Scope and Mechanistic Studies
其他题名: N-芳基膦氮配体参与的铱催化的不对称烯丙基烷基化反应: 范围与机理研究
作者: Liu WB(刘文博) ; Zheng C(郑超) ; Zhuo CX(卓春祥) ; Dai LX(戴立信) ; You SL(游书力)
通讯作者: 游书力
刊名: J. Am. Chem. Soc.
发表日期: 2012
卷: 134, 期:10, 页:4812-4821
收录类别: SCI
部门归属: 中科院上海有机化学研究所
英文摘要: A series of N-aryl phosphoramidite ligands has been synthesized and applied to iridium-catalyzed allylic alkylation reactions, offering high regio- and enantioselectivities for a wide variety of substrates. These ligands feature the synthetic convenience and good tolerance of the ortho-substituted cinnamyl carbonates. Mechanistic studies, including DFT calculations and X-ray crystallographic analyses of the (pi-allyl)-Ir complexes, reveal that the active iridacycle is formed via C(sp(2))-H bond activation.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000301990600057
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/28011
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Liu WB,Zheng C,Zhuo CX,et al. Iridium-Catalyzed Allylic Alkylation Reaction with N-Aryl Phosphoramidite Ligands: Scope and Mechanistic Studies[J]. J. Am. Chem. Soc.,2012,134(10):4812-4821.
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