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学科主题: 金属有机化学
题名: Synthesis, Characterization, and Highly Selective Ethylene Dimerization to 1-Butene of [O-NX]Ni(II) Complexes
其他题名: [O-NX]Ni(II)配合物的合成, 表征以及高选择性二聚合成1-丁烯
作者: Xu CJ(许崇杰) ; Shen Q(沈琪) ; Sun XL(孙秀丽) ; Tang Y(唐勇)
通讯作者: 孙秀丽
刊名: Chin. J. Chem.
发表日期: 2012
卷: 30, 期:5, 页:1105-1113
收录类别: SCI
部门归属: 苏州大学; 中科院上海有机化学研究所
英文摘要: A series of nickel(II) complexes have been synthesized and characterized. Molecular structure analysis exhibits that a square planar geometry around nickel is adopted. Upon activation with MAO, these nickel(II) complexes are efficient in catalyzing the ethylene dimerization, providing 1-butene with an activity of up to 1.4 x 107 g/(mol.h.atm). The heteroatoms of the sidearm in the complexes were proved to have great impact on the activity and selectivity of 1-butene.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000304045600017
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27991
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Xu CJ,Shen Q,Sun XL,et al. Synthesis, Characterization, and Highly Selective Ethylene Dimerization to 1-Butene of [O-NX]Ni(II) Complexes[J]. Chin. J. Chem.,2012,30(5):1105-1113.
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