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学科主题: 金属有机化学
题名: Efficient Chiral Monophosphorus Ligands for Asymmetric Suzuki-Miyaura Coupling Reactions
其他题名: 高效手性单膦配体在不对称Suzuki-Miyaura偶联反应中的应用
作者: Tang WJ(汤文军) ; PATEL NITINCHANDRA D ; Xu GQ(徐广庆) ; Xu XB(徐晓冰) ; SAVOIE JOLAINE ; MA SHENGLI ; HAO MINGHONG ; KESHIPEDDY SANTOSH ; CAPACCI ANDREW G ; WEI XUDONG ; ZHANG YONGDA ; GAO JOE J ; LI WENJIE ; RODRIGUEZ SONIA ; LU BRUCE Z ; YEE NATHAN K ; SENANAYAKE CHRIS H
通讯作者: 汤文军
刊名: Org. Lett.
发表日期: 2012
卷: 14, 期:9, 页:2258-2261
收录类别: SCI
部门归属: 中科院上海有机化学研究所; 美国Boehringer Ingelheim Pharmaceut Inc
英文摘要: A series of novel P-chiral monophosphorus ligands exhibit efficiency in asymmetric Suzuki-Miyaura coupling reactions, enabling the construction of an array of chiral biaryl products In high yields and excellent enantioselectivities (up to 96% ee) under mild conditions. The carbonyl-benzooxazolidinone moiety in these chiral biaryl products allows facile derivatization for further synthetic applications. A computational study has revealed that a pi-pi interaction between the two coupling partners can enhance the enantioselectivity of the coupling reaction.
语种: 英语
相关网址: 查看原文
WOS记录号: WOS:000303492200017
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内容类型: 期刊论文
URI标识: http://ir.sioc.ac.cn/handle/331003/27987
Appears in Collections:金属有机化学国家重点实验室_期刊论文

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Recommended Citation:
Tang WJ,PATEL NITINCHANDRA D,Xu GQ,et al. Efficient Chiral Monophosphorus Ligands for Asymmetric Suzuki-Miyaura Coupling Reactions[J]. Org. Lett.,2012,14(9):2258-2261.
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